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Abstract | Cited by

The controlled synthesis of poly(3-hexylthiophene)s (P3HTs) with number-average molecular weights (Mns) up to 350 kg mol−1 has been realized with Ni(IPr)(acac)2 as the catalyst.

Graphical abstract: Controlled synthesis of high molecular weight poly(3-hexylthiophene)s via Kumada catalyst transfer polycondensation with Ni(IPr)(acac)2 as the catalyst

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