Issue 5, 2015

Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(ii) bisporphyrin

Abstract

For the first time, a clear and unambiguous rationalization of chirality induction, inversion and subsequent amplification process has been demonstrated for the 1 : 1 sandwich and 2 : 3 host–guest supramolecular complexes consisting of Zn(II) host and chiral diamines as guests that has so far remained the most outstanding issue for the chirogenic process.

Graphical abstract: Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(ii) bisporphyrin

Supplementary files

Article information

Article type
Communication
Submitted
08 Oct 2014
Accepted
10 Nov 2014
First published
10 Nov 2014

Chem. Commun., 2015,51, 895-898

Author version available

Step-wise induction, amplification and inversion of molecular chirality through the coordination of chiral diamines with Zn(II) bisporphyrin

S. A. Ikbal, S. Brahma and S. P. Rath, Chem. Commun., 2015, 51, 895 DOI: 10.1039/C4CC07955H

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