Direct C–H arylation and alkenylation of 4,4′-dialkylimidazolones with a broad range of halides under palladium and copper catalysis have been developed. This methodology is applied to the preparation of recently discovered fatty acid synthetase (FAS) inhibitors.
M. Muselli, C. Baudequin, C. Hoarau and L. Bischoff, Chem. Commun., 2015, 51, 745 DOI: 10.1039/C4CC07917E
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