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Abstract | Cited by

A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C–H arylation of N-aryl glycine esters with aryl boric acids in the presence of a chiral Pd(II)-catalyst has been developed. This work successfully integrates the direct C–H oxidation with asymmetric arylation and exhibits excellent enantioselectivity.

Graphical abstract: Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling

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