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Issue 25, 2015
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Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

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Abstract

The competence between the possible reaction pathways in the reaction of different cycloalkanes and o-benzyne has been computationally explored. Systems able to undergo complete desaturation by consecutive double hydrogen atom transfer reactions are suggested.

Graphical abstract: Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

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Article information


Submitted
16 Sep 2014
Accepted
23 Oct 2014
First published
23 Oct 2014

Chem. Commun., 2015,51, 5302-5305
Article type
Communication
Author version available

Is it possible to achieve a complete desaturation of cycloalkanes promoted by o-benzyne?

F. Cervantes-Navarro, A. de Cózar, F. P. Cossío, M. A. Fernández-Herrera, G. Merino and I. Fernández, Chem. Commun., 2015, 51, 5302
DOI: 10.1039/C4CC07311H

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