Pd-catalyzed asymmetric allylic sulfonation of di-aryl-substituted allylic acetates with sodium sulfite (Na2SO3) in THF–H2O at room temperature was described. This method directly provided allylic sulfonic acids in up to excellent yield and enantioselectivity.
W. Liu, X. Zhao, H. Zhang and L. Zhang, Chem. Commun., 2015, 51, 655 DOI: 10.1039/C4CC06945E
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