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Issue 15, 2015
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Highly regioselective osmium-catalyzed hydroformylation

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Abstract

The first highly regioselective and general osmium-catalyzed hydroformylation of olefins to aldehydes is reported. The combination of Os3(CO)12 and imidazoyl-substituted phosphine ligands allows n-selective (up to 99%) hydroformylation of bulk aliphatic as well as functional alkenes in good yields (64–87%).

Graphical abstract: Highly regioselective osmium-catalyzed hydroformylation

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Article information


Submitted
21 Jul 2014
Accepted
10 Dec 2014
First published
10 Dec 2014

Chem. Commun., 2015,51, 3080-3082
Article type
Communication

Highly regioselective osmium-catalyzed hydroformylation

L. Wu, Q. Liu, A. Spannenberg, R. Jackstell and M. Beller, Chem. Commun., 2015, 51, 3080
DOI: 10.1039/C4CC05626D

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