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Issue 5, 2015
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Supramolecular ionic networks with superior thermal and transport properties based on novel delocalized di-anionic compounds

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Abstract

Supramolecular ionic networks based on highly delocalized dianions having (trifluoromethane-sulfonyl)imide, (propylsulfonyl)methanide and (cyano-propylsulfonyl)imide groups were developed and their physical properties were examined in detail. Most of the synthesized compounds were semi-crystalline possessing Tm values close to 100 °C; however, amorphous networks were also obtained using aromatic asymmetric dianions. Rheological measurements in temperature sweep tests at a constant frequency confirmed two different behaviors: a fast melting close to the Tm for semi-crystalline materials and a thermoreversible network for liquid transition for the amorphous supramolecular ionic networks. It was found that the amorphous ionic networks showed significantly higher ionic conductivity (10−3 S cm−1 at 100 °C) than the crystalline ionic networks (10−6 S cm−1) and previously reported amorphous citrate ionic networks (10−5 S cm−1). The supramolecular ionic networks containing hydrophobic (trifluoromethanesulfonyl)imide groups demonstrated improved water stability and higher thermal stability than the previously synthesized carboxylate ones. Noticeably, the obtained amorphous supramolecular ionic networks combine not only high ionic conductivity and thermal stability, but also self-healing properties into the same material.

Graphical abstract: Supramolecular ionic networks with superior thermal and transport properties based on novel delocalized di-anionic compounds

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Supplementary files

Article information


Submitted
29 Oct 2014
Accepted
26 Nov 2014
First published
26 Nov 2014

J. Mater. Chem. A, 2015,3, 2338-2343
Article type
Paper
Author version available

Supramolecular ionic networks with superior thermal and transport properties based on novel delocalized di-anionic compounds

M. A. Aboudzadeh, A. S. Shaplov, G. Hernandez, P. S. Vlasov, E. I. Lozinskaya, C. Pozo-Gonzalo, M. Forsyth, Y. S. Vygodskii and D. Mecerreyes, J. Mater. Chem. A, 2015, 3, 2338
DOI: 10.1039/C4TA05792A

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