Jump to main content
Jump to site search

Issue 27, 2015
Previous Article Next Article

Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

Author affiliations

Abstract

A simple generation method of carbon radicals via 1e-oxidation of organotrifluoroborates and carboxylic acids by the action of an organophotoredox catalyst, 9-mesityl-10-methylacridinium perchlorate ([Acr+–Mes]ClO4), has been developed. This organophotocatalytic protocol is amenable to radical C–C bond formation with electron-deficient olefins.

Graphical abstract: Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Dec 2014, accepted on 12 Feb 2015 and first published on 13 Feb 2015


Article type: Communication
DOI: 10.1039/C5RA01826A
RSC Adv., 2015,5, 21297-21300

  •   Request permissions

    Redox-economical radical generation from organoborates and carboxylic acids by organic photoredox catalysis

    T. Chinzei, K. Miyazawa, Y. Yasu, T. Koike and M. Akita, RSC Adv., 2015, 5, 21297
    DOI: 10.1039/C5RA01826A

Search articles by author

Spotlight

Advertisements