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Issue 30, 2015
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Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

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Abstract

The first facile and practical silver-mediated cascade reaction of arylpropiolic acids with diarylphosphine oxides has been developed, providing a general, one step approach to structurally sophisticated 2-phosphinobenzo[b]phosphole oxide frameworks of importance in materials science via sequential decarboxylative C–P cross-coupling and C–H/P–H functionalization with operational simplicity and excellent functional group compatibility.

Graphical abstract: Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

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Publication details

The article was received on 12 May 2015, accepted on 17 Jun 2015 and first published on 17 Jun 2015


Article type: Paper
DOI: 10.1039/C5OB00959F
Org. Biomol. Chem., 2015,13, 8221-8231

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    Ag-mediated cascade decarboxylative coupling and annulation: a convenient route to 2-phosphinobenzo[b]phosphole oxides

    G. Hu, Y. Zhang, J. Su, Z. Li, Y. Gao and Y. Zhao, Org. Biomol. Chem., 2015, 13, 8221
    DOI: 10.1039/C5OB00959F

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