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Issue 14, 2015
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Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity

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Abstract

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereoselectivities (all dr > 99 : 1), especially for ketimine substrates.

Graphical abstract: Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity

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Article information


Submitted
15 Feb 2015
Accepted
02 Mar 2015
First published
02 Mar 2015

Org. Biomol. Chem., 2015,13, 4174-4178
Article type
Communication
Author version available

Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines: dual stereocontrol with nearly perfect diastereoselectivity

Y. Zhao, Q. Liu, P. Tian, J. Tao and G. Lin, Org. Biomol. Chem., 2015, 13, 4174
DOI: 10.1039/C5OB00322A

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