Copper-catalyzed asymmetric allylation of chiral N-tert-butanesulfinyl imines has been described. Dual stereocontrol, through the combination of a chiral auxiliary and a chiral copper complex, has played an important role in achieving the nearly perfect diastereoselectivities (all dr > 99 : 1), especially for ketimine substrates.
Y. Zhao, Q. Liu, P. Tian, J. Tao and G. Lin, Org. Biomol. Chem., 2015, 13, 4174 DOI: 10.1039/C5OB00322A
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