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Issue 14, 2015
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Oxidative cleavage of allyl ethers by an oxoammonium salt

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Abstract

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

Graphical abstract: Oxidative cleavage of allyl ethers by an oxoammonium salt

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Supplementary files

Article information


Submitted
06 Feb 2015
Accepted
25 Feb 2015
First published
25 Feb 2015

Org. Biomol. Chem., 2015,13, 4255-4259
Article type
Paper

Oxidative cleavage of allyl ethers by an oxoammonium salt

C. B. Kelly, J. M. Ovian, R. M. Cywar, T. R. Gosselin, R. J. Wiles and N. E. Leadbeater, Org. Biomol. Chem., 2015, 13, 4255
DOI: 10.1039/C5OB00270B

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