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Issue 2, 2015
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Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

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Abstract

A highly efficient catalytic asymmetric alkynylation of prochiral CH2 groups in tetrahydroisoquinoline was developed using copper catalyzed cross-dehydrogenative-coupling of sp3 and sp C–H bonds with the assistance of a photocatalyst and visible light.

Graphical abstract: Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

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Supplementary files

Article information


Submitted
07 Oct 2014
Accepted
16 Oct 2014
First published
16 Oct 2014

Org. Biomol. Chem., 2015,13, 447-451
Article type
Paper
Author version available

Efficient merging of copper and photoredox catalysis for the asymmetric cross-dehydrogenative-coupling of alkynes and tetrahydroisoquinolines

I. Perepichka, S. Kundu, Z. Hearne and C. Li, Org. Biomol. Chem., 2015, 13, 447 DOI: 10.1039/C4OB02138J

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