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Issue 30, 2015
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Self-assembly and continuous growth of hexagonal graphene flakes on liquid Cu

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Abstract

Graphene growth on liquid Cu has received great interest, owing to the self-assembly behavior of hexagonal graphene flakes with aligned orientation and to the possibility of forming a single grain of graphene through a commensurate growth of these graphene flakes. Here, we propose and demonstrate a two-step growth process which allows the formation of self-assembled, completely continuous graphene on liquid Cu. After the formation of full coverage on the liquid Cu, grain boundaries were revealed via selective hydrogen etching and the original grain boundaries were clearly resolved. This result indicates that, while the flakes self-assembled with the same orientation, there still remain structural defects, gaps and voids that were not resolved by optical microscopy or scanning electron microscopy. To overcome this limitation, the two-step growth process was employed, consisting of a sequential process of a normal single-layer graphene growth and self-assembly process with a low carbon flux, followed by the final stage of graphene growth at a high degree of supersaturation with a high carbon flux. Continuity of the flakes was verified via hydrogen etching and a NaCl-assisted oxidation process, as well as by measuring the electrical properties of the graphene grown by the two-step process. Two-step growth can provide a continuous graphene layer, but commensurate stitching should be further studied.

Graphical abstract: Self-assembly and continuous growth of hexagonal graphene flakes on liquid Cu

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Publication details

The article was received on 21 May 2015, accepted on 19 Jun 2015 and first published on 25 Jun 2015


Article type: Communication
DOI: 10.1039/C5NR03352G
Nanoscale, 2015,7, 12820-12827

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    Self-assembly and continuous growth of hexagonal graphene flakes on liquid Cu

    S. Cho, M. Kim, M. Kim, K. Kim, H. Kim, D. Lee, S. Lee and K. Kim, Nanoscale, 2015, 7, 12820
    DOI: 10.1039/C5NR03352G

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