Jump to main content
Jump to site search

Issue 13, 2015
Previous Article Next Article

Contact angle and adsorption energies of nanoparticles at the air–liquid interface determined by neutron reflectivity and molecular dynamics

Author affiliations

Abstract

Understanding how nanomaterials interact with interfaces is essential to control their self-assembly as well as their optical, electronic, and catalytic properties. We present here an experimental approach based on neutron reflectivity (NR) that allows the in situ measurement of the contact angles of nanoparticles adsorbed at fluid interfaces. Because our method provides a route to quantify the adsorption and interfacial energies of the nanoparticles in situ, it circumvents problems associated with existing indirect methods, which rely on the transport of the monolayers to substrates for further analysis. We illustrate the method by measuring the contact angle of hydrophilic and hydrophobic gold nanoparticles, coated with perdeuterated octanethiol (d-OT) and with a mixture of d-OT and mercaptohexanol (MHol), respectively. The contact angles were also calculated via atomistic molecular dynamics (MD) computations, showing excellent agreement with the experimental data. Our method opens the route to quantify the adsorption of complex nanoparticle structures adsorbed at fluid interfaces featuring different chemical compositions.

Graphical abstract: Contact angle and adsorption energies of nanoparticles at the air–liquid interface determined by neutron reflectivity and molecular dynamics

Back to tab navigation

Supplementary files

Article information


Submitted
27 Jan 2015
Accepted
17 Feb 2015
First published
20 Feb 2015

Nanoscale, 2015,7, 5665-5673
Article type
Paper
Author version available

Contact angle and adsorption energies of nanoparticles at the air–liquid interface determined by neutron reflectivity and molecular dynamics

J. Reguera, E. Ponomarev, T. Geue, F. Stellacci, F. Bresme and M. Moglianetti, Nanoscale, 2015, 7, 5665
DOI: 10.1039/C5NR00620A

Social activity

Search articles by author

Spotlight

Advertisements