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Issue 1, 2015
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Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions

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Abstract

Addition of anions to perfluorinated 1,1′-biphenyl 1 or naphthalene 2 results in a shift of the 19F NMR signals. However, any specific interaction cannot be assigned to this effect. In order to study the interaction in more detail, the salt derivatives 3 and 4 were prepared and studied by single crystal X-ray diffraction revealing weak anion–π interactions in the solid state.

Graphical abstract: Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions

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Article information


Submitted
25 Sep 2014
Accepted
03 Nov 2014
First published
19 Nov 2014

New J. Chem., 2015,39, 746-749
Article type
Paper

Perfluoro-1,1′-biphenyl and perfluoronaphthalene and their derivatives as π-acceptors for anions

H. Yi, M. Albrecht, A. Valkonen and K. Rissanen, New J. Chem., 2015, 39, 746
DOI: 10.1039/C4NJ01654H

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