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Volume 180, 2015

Aqueous solution/metal interfaces investigated in operando by photoelectron spectroscopy

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Abstract

We describe a new in operando approach for the investigation of heterogeneous processes at solid/liquid interfaces with elemental and chemical specificity which combines the preparation of thin liquid films using the meniscus method with standing wave ambient pressure X-ray photoelectron spectroscopy [Nemšák et al., Nat. Commun., 5, 5441 (2014)]. This technique provides information about the chemical composition across liquid/solid interfaces with sub-nanometer depth resolution and under realistic conditions of solution composition and concentration, pH, as well as electrical bias. In this article, we discuss the basics of the technique and present the first results of measurements on KOH/Ni interfaces.

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Article information


Submitted
07 Jan 2015
Accepted
16 Jan 2015
First published
16 Jan 2015

Faraday Discuss., 2015,180, 35-53
Article type
Paper
Author version available

Aqueous solution/metal interfaces investigated in operando by photoelectron spectroscopy

O. Karslıoğlu, S. Nemšák, I. Zegkinoglou, A. Shavorskiy, M. Hartl, F. Salmassi, E. M. Gullikson, M. L. Ng, Ch. Rameshan, B. Rude, D. Bianculli, A. A. Cordones, S. Axnanda, E. J. Crumlin, P. N. Ross, C. M. Schneider, Z. Hussain, Z. Liu, C. S. Fadley and H. Bluhm, Faraday Discuss., 2015, 180, 35 DOI: 10.1039/C5FD00003C

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