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Issue 1, 2015
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Co@NH2-MIL-125(Ti): cobaloxime-derived metal–organic framework-based composite for light-driven H2 production

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Abstract

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal–organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

Graphical abstract: Co@NH2-MIL-125(Ti): cobaloxime-derived metal–organic framework-based composite for light-driven H2 production

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Article information


Submitted
08 Sep 2014
Accepted
17 Nov 2014
First published
18 Nov 2014

Energy Environ. Sci., 2015,8, 364-375
Article type
Paper

Co@NH2-MIL-125(Ti): cobaloxime-derived metal–organic framework-based composite for light-driven H2 production

M. A. Nasalevich, R. Becker, E. V. Ramos-Fernandez, S. Castellanos, S. L. Veber, M. V. Fedin, F. Kapteijn, J. N. H. Reek, J. I. van der Vlugt and J. Gascon, Energy Environ. Sci., 2015, 8, 364
DOI: 10.1039/C4EE02853H

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