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Issue 41, 2015
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Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(ii)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions

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Abstract

A lipophilic and electron-rich phthalocyanine (α,α′-n-OC5H11)8-H2Pc and its nickel(II) complex (α,α′-n-OC5H11)8-Ni(II)Pc have been synthesized and characterized. Detailed analyses of the electronic structure were carried out by spectroscopy, electrochemistry, spectroelectrochemistry, and TD-DFT calculations. A series of experiments demonstrate that the (α,α′-n-OC5H11)8-Ni(II)Pc complex can be used as a catalyst for highly efficient carbonyl reductions.

Graphical abstract: Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(ii)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions

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Article information


Submitted
24 Aug 2015
Accepted
13 Sep 2015
First published
17 Sep 2015

Dalton Trans., 2015,44, 18237-18246
Article type
Paper

Lipophilic M(α,α′-OC5H11)8phthalocyanines (M = H2 and Ni(II)): synthesis, electronic structure, and their utility for highly efficient carbonyl reductions

Y. Jiang, M. Li, X. Liang, J. Mack, M. Wildervanck, T. Nyokong, M. Qin and W. Zhu, Dalton Trans., 2015, 44, 18237
DOI: 10.1039/C5DT03256C

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