Jump to main content
Jump to site search

Issue 41, 2015
Previous Article Next Article

Iron(ii) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: mononuclear complexes

Author affiliations

Abstract

The synthesis of new Schiff base-like ligands with extended π-system and their iron complexes is described. Some of the iron(II) complexes with N-heterocycles as axial ligands show spin crossover behaviour. The influence of the extended aromatic system on cooperative interactions is investigated by single crystal X-ray structure analysis, X-ray powder diffraction, and magnetic measurements. A combination of C–H⋯π and C–H⋯O interactions is made responsible for up to 10 K wide thermal hysteresis loops.

Graphical abstract: Iron(ii) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: mononuclear complexes

Back to tab navigation

Supplementary files

Publication details

The article was received on 07 Aug 2015, accepted on 22 Sep 2015 and first published on 22 Sep 2015


Article type: Paper
DOI: 10.1039/C5DT03048J
Dalton Trans., 2015,44, 18065-18077
  • Open access: Creative Commons BY license
  •   Request permissions

    Iron(II) spin crossover complexes with diaminonaphthalene-based Schiff base-like ligands: mononuclear complexes

    C. Lochenie, J. Heinz, W. Milius and B. Weber, Dalton Trans., 2015, 44, 18065
    DOI: 10.1039/C5DT03048J

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements