Chiral ligand-modified polyoxometalates (POMs) were successfully synthesized by the introduction of BINOL into the dititanium-substituted POM in an organic medium and characterized by X-ray crystallography, spectroscopy, and elemental analyses. These BINOL-modified POMs were stable in the solution state and showed catalytic activity for asymmetric oxidation of thioanisole.
R. Ishimoto, K. Kamata, K. Suzuki, K. Yamaguchi and N. Mizuno, Dalton Trans., 2015, 44, 10947 DOI: 10.1039/C5DT01338K
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