Issue 11, 2015
From the journal:

Dalton Transactions

Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates†

Rebecca L. Melenab  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6
E-mail: dstephan@chem.utoronto.ca

b School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff, Cymru/Wales

Abstract

The 1,3-dipolar cycloaddition reactions of the electron deficient boron azide, (C6F5)2BN3 (1) with the electron-poor acetylenes RO2CC[triple bond, length as m-dash]CCO2R (R = Me, Et) afforded the new mono- and bis-1,2,3-triazole derivatives 5 and 6.

Graphical abstract: Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates

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Article information

DOI
https://doi.org/10.1039/C5DT00316D
Article type
Communication
Submitted
22 Jan 2015
Accepted
10 Feb 2015
First published
11 Feb 2015

Dalton Trans., 2015,44, 5045-5048

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Cycloaddition reactions of (C6F5)2BN3 with dialkyl acetylenedicarboxylates

R. L. Melen and D. W. Stephan, Dalton Trans., 2015, 44, 5045 DOI: 10.1039/C5DT00316D

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