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Issue 5, 2015
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Copper-promoted aerial oxidation of benzothiadiazines: access to benzothiadiazine S-oxide heterocycles

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Abstract

CuII-promoted aerial oxidation of a series of benzothiadiazines (1) under ambient conditions affords the first structurally characterised examples of thiadiazine S-oxides (2). The isolation of the homoleptic CuII 3-(2′-pyridyl)benzothiadiazide-S-oxide complex provides insight into the reaction mechanism.

Graphical abstract: Copper-promoted aerial oxidation of benzothiadiazines: access to benzothiadiazine S-oxide heterocycles

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Article information


Submitted
11 Nov 2014
Accepted
10 Dec 2014
First published
12 Dec 2014

Dalton Trans., 2015,44, 2071-2074
Article type
Communication
Author version available

Copper-promoted aerial oxidation of benzothiadiazines: access to benzothiadiazine S-oxide heterocycles

E. R. Clark, J. J. Hayward, B. J. Leontowicz, M. U. Anwar, M. Pilkington and J. M. Rawson, Dalton Trans., 2015, 44, 2071
DOI: 10.1039/C4DT03467H

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