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Issue 5, 2015

A porous metal–organic framework containing multiple active Cu2+ sites for highly efficient cross dehydrogenative coupling reaction

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Abstract

A novel 3D porous metal–organic framework was constructed from imidazole carboxylate linkers and copper(II) nodes, which in situ generates multiple active CuII sites in the nanosized channel walls for highly efficient cross dehydrogenative coupling reaction between 1,2,3,4-tetrahydroisoquinoline derivatives and nitroalkanes that are superior to the simple copper salts.

Graphical abstract: A porous metal–organic framework containing multiple active Cu2+ sites for highly efficient cross dehydrogenative coupling reaction

Supplementary files

Article information


Submitted
03 Nov 2014
Accepted
01 Dec 2014
First published
04 Dec 2014

Dalton Trans., 2015,44, 2038-2041
Article type
Communication

A porous metal–organic framework containing multiple active Cu2+ sites for highly efficient cross dehydrogenative coupling reaction

S. Zhu, S. Ou, M. Zhao, H. Shen and C. Wu, Dalton Trans., 2015, 44, 2038 DOI: 10.1039/C4DT03371J

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