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Issue 15, 2015
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Design and fabrication of mesoporous heterogeneous basic catalysts

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Abstract

Mesoporous solid bases are extremely desirable in green catalytic processes, due to their advantages of accelerated mass transport, negligible corrosion, and easy separation. Great progress has been made in mesoporous solid bases in the last decade. In addition to their wide applications in the catalytic synthesis of organics and fine chemicals, mesoporous solid bases have also been used in the field of energy and environmental catalysis. Development of mesoporous solid bases is therefore of significant importance from both academic and practical points of view. In this review, we provide an overview of the recent advances in mesoporous solid bases, which is basically grouped by the support type and each category is illustrated with typical examples. Cooperative catalysts derived from the incorporation of additional functionalities (i.e. acid and metal) into mesoporous solid bases are also included. The fundamental principles of how to design and fabricate basic materials with mesostructure are highlighted. The mechanism of the formation of basic sites in different mesoporous systems is discussed as well.

Graphical abstract: Design and fabrication of mesoporous heterogeneous basic catalysts

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Publication details

The article was received on 31 Jan 2015 and first published on 05 Jun 2015


Article type: Review Article
DOI: 10.1039/C5CS00090D
Chem. Soc. Rev., 2015,44, 5092-5147

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    Design and fabrication of mesoporous heterogeneous basic catalysts

    L. Sun, X. Liu and H. Zhou, Chem. Soc. Rev., 2015, 44, 5092
    DOI: 10.1039/C5CS00090D

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