Jump to main content
Jump to site search

Issue 5, 2015
Previous Article Next Article

Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

Author affiliations

Abstract

The transition metal-catalyzed C–H functionalization with hydroxylamine derivatives serving as both reactants and internal oxidants has attracted a lot of interest. These reactions obviate the need for external oxidants and therefore result in high reactivity and selectivity, as well as excellent functional group tolerance under mild reaction conditions, and moreover, water, methanol or carboxylic acid is generally released as the by-product, thus leading to reduced waste. This review focuses on the transition metal-catalyzed oxidative C–H functionalization of N-oxyenamine internal oxidants, with an emphasis on the scope and limitations, as well as the mechanisms of these reactions.

Graphical abstract: Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

Back to tab navigation

Article information


Submitted
31 Aug 2014
First published
24 Nov 2014

Chem. Soc. Rev., 2015,44, 1155-1171
Article type
Review Article
Author version available

Transition metal-catalyzed C–H functionalization of N-oxyenamine internal oxidants

H. Huang, X. Ji, W. Wu and H. Jiang, Chem. Soc. Rev., 2015, 44, 1155
DOI: 10.1039/C4CS00288A

Social activity

Search articles by author

Spotlight

Advertisements