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Issue 29, 2015
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1D iron(ii) spin crossover coordination polymers with 3,3′-azopyridine – kinetic trapping effects and spin transition above room temperature

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Abstract

Two new iron(II) 1D coordination polymers with spin crossover behaviour were synthesised using 3,3′-azopyridine as bridging axial ligand and N2O2 coordinating Schiff base-like equatorial ligands. The X-ray structures of both complexes were solved revealing very different packing patterns for the two complexes. Magnetic measurements reveal a spin transition with hysteresis and kinetic trapping effects at lower temperatures for one complex and a spin transition above room temperature for the second complex.

Graphical abstract: 1D iron(ii) spin crossover coordination polymers with 3,3′-azopyridine – kinetic trapping effects and spin transition above room temperature

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Publication details

The article was received on 23 Apr 2015, accepted on 19 May 2015 and first published on 22 May 2015


Article type: Paper
DOI: 10.1039/C5CE00800J
CrystEngComm, 2015,17, 5389-5395
  • Open access: Creative Commons BY license
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    1D iron(II) spin crossover coordination polymers with 3,3′-azopyridine – kinetic trapping effects and spin transition above room temperature

    S. Schönfeld, C. Lochenie, P. Thoma and B. Weber, CrystEngComm, 2015, 17, 5389
    DOI: 10.1039/C5CE00800J

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