Issue 22, 2015
From the journal:

CrystEngComm

Green synthesis of zirconium-MOFs†

Helge Reinsch,a   Bart Bueken,b   Frederik Vermoortele,b   Ivo Stassen,b   Alexandra Lieb,c   Karl-Petter Lilleruda  and  Dirk De Vos*b  

* Corresponding authors

a Department of Chemistry, University of Oslo, P.O. Box 1033 Blindern, 0315 Oslo, Norway

b Centre for Surface Chemistry and Catalysis, University of Leuven, Kasteelkpark Arenberg 23, 3001 Heverlee, Belgium
E-mail: dirk.devos@biw.kuleuven.be
Fax: +32 16 3 21998
Tel: +32 16 32 16 39

c Institut für Chemie, Universitätsplatz 2, 39106 Magdeburg, Germany

Abstract

The synthesis of Zr-MOFs under green, industrially feasible conditions was investigated. Two new compounds with bcu-topology and the fluorinated analogue of UiO-66 exhibiting fcu-topology were obtained and characterised. All products exhibit permanent porosity. In the bcu-frameworks the interaction with sulfate anions apparently induces an unusual eightfold connectivity of the Zr cluster.

Graphical abstract: Green synthesis of zirconium-MOFs

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Article information

DOI
https://doi.org/10.1039/C5CE00618J
Article type
Communication
Submitted
29 Mar 2015
Accepted
23 Apr 2015
First published
30 Apr 2015
This article is Open Access
Creative Commons BY license

CrystEngComm, 2015,17, 4070-4074

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Green synthesis of zirconium-MOFs

H. Reinsch, B. Bueken, F. Vermoortele, I. Stassen, A. Lieb, K. Lillerud and D. De Vos, CrystEngComm, 2015, 17, 4070 DOI: 10.1039/C5CE00618J

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