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Issue 5, 2015
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Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks

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Abstract

The host–guest chemistry between a series of anionic MOFs and their trapped counterions was investigated by single crystal XRD. The PCN-514 series contains crystallographically identifiable metal complexes trapped in the pores, where their formation is controlled by the size and shape of the MOF pores. A change in the structure and pore size of PCN-518 indicates that the existence of guest molecules may reciprocally affect the formation of host MOFs.

Graphical abstract: Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks

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Publication details

The article was received on 13 Nov 2014, accepted on 06 Dec 2014 and first published on 09 Dec 2014


Article type: Communication
DOI: 10.1039/C4CE02261K
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CrystEngComm, 2015,17, 996-1000
  • Open access: Creative Commons BY-NC license
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    Pore-controlled formation of 0D metal complexes in anionic 3D metal–organic frameworks

    M. Zhang, M. Bosch and H. Zhou, CrystEngComm, 2015, 17, 996
    DOI: 10.1039/C4CE02261K

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

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