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Issue 32, 2015
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Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid

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Abstract

Self-standing thiol (−SH) groups within a Zr(IV)-based metal–organic framework (MOF) anchor Pd(II) atoms for catalytic applications: the spatial constraint prevents the thiol groups from sealing off/poisoning the Pd(II) center, while the strong Pd–S bond precludes Pd leaching, enabling multiple cycles of heterogeneous catalysis to be executed.

Graphical abstract: Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid

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Submitted
07 Jan 2015
Accepted
26 Feb 2015
First published
27 Feb 2015

Chem. Commun., 2015,51, 6917-6920
Article type
Communication
Author version available

Tackling poison and leach: catalysis by dangling thiol–palladium functions within a porous metal–organic solid

B. Gui, K. Yee, Y. Wong, S. Yiu, M. Zeller, C. Wang and Z. Xu, Chem. Commun., 2015, 51, 6917
DOI: 10.1039/C5CC00140D

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