Issue 94, 2015
From the journal:

Chemical Communications

Palladium-catalyzed dearomative cyclization by a norbornene-mediated sequence: a route to spiroindolenine derivatives†

Xin-Xing Wu,a   Yi Shen,a   Wen-Long Chen,a   Si Chen,a   Peng-Fei Xu*a  and  Yong-Min Liang*a  

* Corresponding authors

a State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, China
E-mail: liangym@lzu.edu.cn, xupf@lzu.edu.cn
Fax: +86-931-8912582
Tel: +86-931-8912582

Abstract

The first palladium-catalyzed dearomative cyclization via a modified Catellani-type C–H functionalization has been realized. The new strategy led to a series of spiroindolenine derivatives bearing an all-carbon quaternary spirocenter from simple aryl halides and substituted indoles.

Graphical abstract: Palladium-catalyzed dearomative cyclization by a norbornene-mediated sequence: a route to spiroindolenine derivatives

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Article information

DOI
https://doi.org/10.1039/C5CC07411H
Article type
Communication
Submitted
03 Sep 2015
Accepted
22 Sep 2015
First published
23 Sep 2015

Chem. Commun., 2015,51, 16798-16801

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Palladium-catalyzed dearomative cyclization by a norbornene-mediated sequence: a route to spiroindolenine derivatives

X. Wu, Y. Shen, W. Chen, S. Chen, P. Xu and Y. Liang, Chem. Commun., 2015, 51, 16798 DOI: 10.1039/C5CC07411H

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