Issue 96, 2015
From the journal:

Chemical Communications

“Fishing” of heteropolyacids into carbonaceous seine via coking†

Vitaly L. Sushkevich,a   Irina I. Ivanova,a   Christine Lancelot,b   Simona Moldovan,c   Ovidiu Ersenc  and  Vitaly V. Ordomsky*b  

* Corresponding authors

a Department of Chemistry Lomonosov Moscow State University, Leninskye Gory 1, bld. 3, 119991 Moscow, Russia

b Unité de Catalyse et de Chimie du Solide UMR 8181 CNRS, Ecole Centrale de Lille, Université de Lille Bât. C3, 59655 Villeneuve d'Ascq, France
E-mail: vitaly.ordomsky@univ-lille1.fr
Fax: +33 03 20 43 69 53

c Department of Surfaces and Interfaces (DSI), 23, rue du Loess BP 43, F-67034 Strasbourg, France

Abstract

The carbon encapsulated tungstophosphoric acid was synthesized by the controlled coking during gas phase reaction of formaldehyde with isobutene. The as-made material showed unique stability toward leaching in the aqueous phase due to localization of HPA clusters inside the porous coke matrix with high activity in the esterification reaction.

Graphical abstract: “Fishing” of heteropolyacids into carbonaceous seine via coking

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Article information

DOI
https://doi.org/10.1039/C5CC07280H
Article type
Communication
Submitted
30 Aug 2015
Accepted
26 Sep 2015
First published
29 Sep 2015

Chem. Commun., 2015,51, 17120-17123

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“Fishing” of heteropolyacids into carbonaceous seine via coking

V. L. Sushkevich, I. I. Ivanova, C. Lancelot, S. Moldovan, O. Ersen and V. V. Ordomsky, Chem. Commun., 2015, 51, 17120 DOI: 10.1039/C5CC07280H

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