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Issue 86, 2015
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Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks

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Abstract

The molecular dynamics of encapsulated cations within perovskite-like coordination polymers [(CH3)3NH][M(N3)3] (M = Mn, Cd) are investigated, which are well controlled by the confined space of a deformable azido framework. The Mn-based compound provides a rare example that features an unvaried/varied rotational energy barrier during its two different structural phase transitions.

Graphical abstract: Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks

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Article information


Submitted
15 Aug 2015
Accepted
01 Sep 2015
First published
01 Sep 2015

Chem. Commun., 2015,51, 15641-15644
Article type
Communication
Author version available

Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks

Z. Du, Y. Sun, S. Chen, B. Huang, Y. Su, T. Xu, W. Zhang and X. Chen, Chem. Commun., 2015, 51, 15641
DOI: 10.1039/C5CC06863K

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