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Issue 89, 2015
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Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front

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Abstract

After passage of a delamination front at a polymer/zinc interface, pH oscillations and oscillations in the quantity of corrosion products are observed. The reason for these oscillations is the low quantity of water in the confined reaction volume, water consumption by oxygen reduction, and water regeneration after precipitation of ZnO.

Graphical abstract: Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front

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Publication details

The article was received on 02 Aug 2015, accepted on 26 Aug 2015 and first published on 26 Aug 2015


Article type: Communication
DOI: 10.1039/C5CC06468F
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Chem. Commun., 2015,51, 16041-16044
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    Solvent-starved conditions in confinement cause chemical oscillations excited by passage of a cathodic delamination front

    D. Iqbal, A. Sarfraz, M. Stratmann and A. Erbe, Chem. Commun., 2015, 51, 16041
    DOI: 10.1039/C5CC06468F

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