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Issue 96, 2015
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Substitution of Co2+ ions into CdS-based molecular clusters

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Abstract

We report on the metal ion exchange between Co2+ and CdS-based molecular clusters. These studies demonstrate that exchange into the smaller [Cd4(SPh)10]2− clusters is facile compared to the larger [Cd10S4(SPh)16]4− and [Cd17S4(SPh)28]2− clusters. This trend correlates with the rate of benzenethiolate interconversion and μ-S2− and μ-SPh content among the clusters.

Graphical abstract: Substitution of Co2+ ions into CdS-based molecular clusters

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Publication details

The article was received on 22 Jul 2015, accepted on 05 Oct 2015 and first published on 05 Oct 2015


Article type: Communication
DOI: 10.1039/C5CC06138E
Chem. Commun., 2015,51, 17096-17099

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    Substitution of Co2+ ions into CdS-based molecular clusters

    S. Pittala, M. J. Mortelliti, F. Kato and K. R. Kittilstved, Chem. Commun., 2015, 51, 17096
    DOI: 10.1039/C5CC06138E

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