Issue 89, 2015

Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

Abstract

Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-à-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.

Graphical abstract: Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

Supplementary files

Article information

Article type
Communication
Submitted
20 Jul 2015
Accepted
11 Sep 2015
First published
11 Sep 2015

Chem. Commun., 2015,51, 16061-16064

Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

N. Sreekanth, M. A. Nazrulla, T. V. Vineesh, K. Sailaja and K. L. Phani, Chem. Commun., 2015, 51, 16061 DOI: 10.1039/C5CC06051F

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