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Issue 75, 2015
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Oxidative inactivation of NiFeSe hydrogenase

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Abstract

We propose a resolution to the paradox that spectroscopic studies of NiFeSe hydrogenase have not revealed any major signal attributable to NiIII states formed upon reaction with O2, despite the fact that two inactive states are formed upon either aerobic or anaerobic oxidation.

Graphical abstract: Oxidative inactivation of NiFeSe hydrogenase

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Supplementary files

Article information


Submitted
16 Jul 2015
Accepted
29 Jul 2015
First published
30 Jul 2015

Chem. Commun., 2015,51, 14223-14226
Article type
Communication
Author version available

Oxidative inactivation of NiFeSe hydrogenase

P. Ceccaldi, M. C. Marques, V. Fourmond, I. C. Pereira and C. Léger, Chem. Commun., 2015, 51, 14223
DOI: 10.1039/C5CC05930E

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