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Issue 80, 2015
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Thermal dimerization of [n]cumulenes (n = 5, 7, 9)

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Abstract

The thermal dimerization of three [n]cumulenes (n = 5, 7, and 9) has been investigated, and a common reactivity pattern is observed that gives radialenes and expanded radialenes through regioselective cycloaddition reactions; all three products are characterized using X-ray crystallography.

Graphical abstract: Thermal dimerization of [n]cumulenes (n = 5, 7, 9)

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Article information


Submitted
09 Jul 2015
Accepted
07 Aug 2015
First published
07 Aug 2015

Chem. Commun., 2015,51, 14877-14880
Article type
Communication
Author version available

Thermal dimerization of [n]cumulenes (n = 5, 7, 9)

D. Wendinger, J. A. Januszewski, F. Hampel and R. R. Tykwinski, Chem. Commun., 2015, 51, 14877
DOI: 10.1039/C5CC05679A

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