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Issue 78, 2015
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Remarkable reactivity of a rhodium(i) boryl complex towards CO2 and CS2: isolation of a carbido complex

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Abstract

The activation of CO2, CS2 as well as of PhNCO at [Rh(Bpin)(PEt3)3] led to C[double bond, length as m-dash]X bond cleavage and the formation of {RhXBpin} species (X = O, S, N). Treatment of the boryl complex [Rh(Bpin)(PEt3)3] with 0.5 equivalents of CS2 resulted in the fragmentation of CS2 and the formation of the remarkable μ-carbido complex trans-[Rh2(μ-C)(SBpin)2(PEt3)4].

Graphical abstract: Remarkable reactivity of a rhodium(i) boryl complex towards CO2 and CS2: isolation of a carbido complex

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Article information


Submitted
07 Jul 2015
Accepted
07 Aug 2015
First published
19 Aug 2015

Chem. Commun., 2015,51, 14613-14616
Article type
Communication

Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex

S. I. Kalläne, T. Braun, M. Teltewskoi, B. Braun, R. Herrmann and R. Laubenstein, Chem. Commun., 2015, 51, 14613
DOI: 10.1039/C5CC05606C

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