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Issue 54, 2015
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Enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles

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Abstract

Rhodium-catalyzed regio- and enantioselective coupling of tetrazoles with allenes are reported. Asymmetric construction of tertiary and quaternary allylic C–N bonds were achieved using a Rh(I)/JoSPOphos catalyst. This method permits the atom-economic synthesis of various valuable N2-allylic tetrazoles.

Graphical abstract: Enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles

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The article was received on 21 May 2015, accepted on 02 Jun 2015 and first published on 02 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04203H
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Chem. Commun., 2015,51, 10861-10863

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    Enantioselective formation of tertiary and quaternary allylic C–N bonds via allylation of tetrazoles

    K. Xu, W. Raimondi, T. Bury and B. Breit, Chem. Commun., 2015, 51, 10861
    DOI: 10.1039/C5CC04203H

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