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Issue 62, 2015
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Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

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Abstract

Gold-catalyzed hydroimination of terminal alkynes, giving rise to anti-Markovnikov adducts concomitant with unstable Markovnikov adducts is described. The elementary step can be applied for the construction of pyridine derivatives from ammonia and alkynes.

Graphical abstract: Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

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Article information


Submitted
19 May 2015
Accepted
24 Jun 2015
First published
24 Jun 2015

This article is Open Access

Chem. Commun., 2015,51, 12419-12422
Article type
Communication

Anti-Markovnikov hydroimination of terminal alkynes in gold-catalyzed pyridine construction from ammonia

L. Wang, L. Kong, Y. Li, R. Ganguly and R. Kinjo, Chem. Commun., 2015, 51, 12419
DOI: 10.1039/C5CC04091D

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