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Issue 62, 2015
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Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

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Abstract

Here we report the removal of chlorine gas from air via a reaction with an amine functionalized metal–organic framework (MOF). It is found that UiO-66-NH2 has the ability to remove 1.24 g of Cl2 per g of MOF via an electrophilic aromatic substitution reaction producing HCl, which is subsequently neutralized by the MOF.

Graphical abstract: Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

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Publication details

The article was received on 07 May 2015, accepted on 30 Jun 2015 and first published on 01 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC03780H
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Chem. Commun., 2015,51, 12474-12477

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    Removal of chlorine gas by an amine functionalized metal–organic framework via electrophilic aromatic substitution

    J. B. DeCoste, M. A. Browe, G. W. Wagner, J. A. Rossin and G. W. Peterson, Chem. Commun., 2015, 51, 12474
    DOI: 10.1039/C5CC03780H

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