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Issue 56, 2015
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Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

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Abstract

A facile and efficient catalytic system based on a mesostructured ceria-supported gold (Au/meso-CeO2) catalyst was developed for the synthesis of various aromatic azo compounds by the reductive coupling of the corresponding nitroaromatics, using CO as the sole deoxygenative reagent, under additive-free and mild reaction conditions.

Graphical abstract: Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

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Supplementary files

Article information


Submitted
15 Apr 2015
Accepted
29 May 2015
First published
01 Jun 2015

Chem. Commun., 2015,51, 11217-11220
Article type
Communication

Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

H. Li, X. Liu, Q. Zhang, S. Li, Y. Liu, H. He and Y. Cao, Chem. Commun., 2015, 51, 11217
DOI: 10.1039/C5CC03134F

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