A solid-phase synthesis for nucleic acid–polymer amphiphiles is developed. Using this strategy, several DNA-b-polymer amphiphiles are synthesized, and their self-assembly in aqueous solution is investigated. This general method can in principle be extended to nearly all polymers synthesized by atom transfer radical polymerization to produce a variety of nucleic acid–polymer conjugates.
F. Jia, X. Lu, X. Tan and K. Zhang, Chem. Commun., 2015, 51, 7843 DOI: 10.1039/C5CC01934F
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