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Probing scalar couplings are essential for structural elucidation in molecular (bio)chemistry. While the measurement of JHH couplings is facilitated by SERF experiments, overcrowded signals represent a significant limitation. Here, a new band selective pure shift SERF allows access to δ1H and JHH with an ultrahigh spectral resolution.

Graphical abstract: Pushing the limits of signal resolution to make coupling measurement easier

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