Issue 24, 2015

Liquid crystalline macrocyclic azacalix[4]pyridine and its complexes with the zinc ion: conformational change from the saddle to flattened shape

Abstract

Substituted with four 3,4,5-tris(alkoxy)benzyl mini-dendrons, azacalix[4]pyridine (1) with the saddle-shaped core is the first liquid crystal (LC) of heteracalixaromatics. Conformational regulation of azacalix[4]pyridine by complexing with the zinc ion leads to a significant change in LC properties.

Graphical abstract: Liquid crystalline macrocyclic azacalix[4]pyridine and its complexes with the zinc ion: conformational change from the saddle to flattened shape

Supplementary files

Article information

Article type
Communication
Submitted
03 Feb 2015
Accepted
18 Feb 2015
First published
18 Feb 2015

Chem. Commun., 2015,51, 5112-5115

Author version available

Liquid crystalline macrocyclic azacalix[4]pyridine and its complexes with the zinc ion: conformational change from the saddle to flattened shape

S. Fa, X. Chen, S. Yang, D. Wang, L. Zhao, E. Chen and M. Wang, Chem. Commun., 2015, 51, 5112 DOI: 10.1039/C5CC01018G

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