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Issue 29, 2015
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Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines

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Abstract

A titanium-catalyzed cis-hydroalumination of propargylic amines with Red-Al is described, which provides an efficient way to produce Z-configured allylic amines in good to excellent yields with high stereoselectivity and good regioselectivity. The hydride-bridged Al/Ti bimetallic species may act as a real catalyst in this reaction.

Graphical abstract: Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines

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Article information


Submitted
02 Feb 2015
Accepted
05 Mar 2015
First published
05 Mar 2015

Chem. Commun., 2015,51, 6426-6429
Article type
Communication
Author version available

Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines

R. Sun, J. Liu, S. Yang, M. Chen, N. Sun, H. Chen, X. Xie, X. You, S. Li and Y. Liu, Chem. Commun., 2015, 51, 6426
DOI: 10.1039/C5CC00950B

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