Issue 24, 2015
From the journal:

Chemical Communications

Multi-responsive metal–organic lantern cages in solution†

Valentina Brega,a   Matthias Zeller,b   Yufan He,a   H. Peter Lua  and  Jeremy K. Klosterman*a  

* Corresponding authors

a Center for Photochemical Sciences, Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA
E-mail: jkloster@bgsu.edu

b STaRBURSTT CyberInstrumentation Consortium, Youngstown State University, Youngstown, OH 44555-3663, USA

Abstract

Soluble copper-based M4L4 lantern-type metal–organic cages bearing internal amines were synthesized. The solution state integrity of the paramagnetic metal–organic cages was demonstrated using NMR, DLS, MS, and AFM spectroscopy. 1D supramolecular pillars of pre-formed cages or covalent host–guest complexes selectively formed upon treatment with 4,4′-bipyridine and acetic anhydride, respectively.

Graphical abstract: Multi-responsive metal–organic lantern cages in solution

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Article information

DOI
https://doi.org/10.1039/C5CC00698H
Article type
Communication
Submitted
24 Jan 2015
Accepted
16 Feb 2015
First published
17 Feb 2015

Chem. Commun., 2015,51, 5077-5080

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Multi-responsive metal–organic lantern cages in solution

V. Brega, M. Zeller, Y. He, H. Peter Lu and J. K. Klosterman, Chem. Commun., 2015, 51, 5077 DOI: 10.1039/C5CC00698H

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