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Issue 26, 2015
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Formation of N3 during interaction of NO with reduced ceria

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Abstract

We show that the first stages of interaction between NO and reduced ceria comprise the formation of azides, N3, with simultaneous oxidation of Ce3+ to Ce4+. This finding imposes revision on some current views of catalytic NO conversion and may contribute to design of new deNOx materials and processes.

Graphical abstract: Formation of N3− during interaction of NO with reduced ceria

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Publication details

The article was received on 18 Jan 2015, accepted on 17 Feb 2015 and first published on 17 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00500K
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Chem. Commun., 2015,51, 5668-5671

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    Formation of N3 during interaction of NO with reduced ceria

    M. Y. Mihaylov, E. Z. Ivanova, H. A. Aleksandrov, P. St. Petkov, G. N. Vayssilov and K. I. Hadjiivanov, Chem. Commun., 2015, 51, 5668
    DOI: 10.1039/C5CC00500K

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