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Issue 26, 2015
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Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

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Abstract

One-pot multiple borylation of phenylhydrazones to a series of novel boron–nitrogen analogues of benzopentalene by the cleavage of C–H bonds with PhBBr2 mediated by NEt3 has been established. The resulting BN benzopentalenes feature unique electronic structures and are luminescent both in solution and the solid state.

Graphical abstract: Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

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Publication details

The article was received on 17 Jan 2015, accepted on 19 Feb 2015 and first published on 19 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00471C
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Chem. Commun., 2015,51, 5732-5734

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    Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

    C. Ma, J. Zhang, J. Li and C. Cui, Chem. Commun., 2015, 51, 5732
    DOI: 10.1039/C5CC00471C

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